NMR SPECTROSCOPY OF PARAMAGNETIC COMPOUNDS - in solution

The application and further development of the NMR method has included studies of paramagnetic molecules in order to determine

NMR SPECTROSCOPY OF PARAMAGNETIC COMPOUNDS - in the solid state

Magic angle spinning (MAS) NMR studies of solid paramagnetic compounds have been carried out on

                Organic radicals (see Figure 7 from ref. 129; see also refs. 142 and 143 - 147)
                Organometallics (see Figure 8 from ref. 154; see also refs. 116, 119, 135, 137, 139, 152)
                Hexacyanometalates (see Figures 9 and 10 from refs. 143 and 161; see also ref. 155)

The aim was to investigate genuine (undiluted) microcrystalline magnetic solids as would be desirable for related materials. Some promising results are the straightforward detection of small spin densities and their sign in high resolution. In addition, the local geometric and magnetic structure and its disorder are accessible.

Multinuclear NMR spectroscopy

Besides 1H and 13C the NMR studies have included the following nuclei  

Nucleus

Entry of publication list

Nucleus

Entry of publication list

2H

89, 91, 102, 105, 114, 121, 122, 123, 129, 137

31P

11, 66, 70, 101, 120, 139, 146

6/7Li

94, 151

71Ga

71

11B

164

113Cd

155, 158

14/15N

78, 143, 160, 163, 164

119Sn

57, 58, 78, 80, 86, 87, 94,
107, 151

19F

101, 139

133Cs

148, 161

27Al

70

207Pb

107

29Si

31, 42, 66, 97, 99, 103, 107, 111,
112, 113, 115, 138, 150, 151